Sustainable, superhydrophobic membranes based on bacterial cellulose for gravity-driven oil/water separation.

Feng-Ping Wang, Xiang-Jun Zhao, Fazli Wahid, Xue-Qing Zhao, Xiao-Tong Qin, He Bai, Yan-Yan Xie, Cheng Zhong, Shi-Ru Jia
Author Information
  1. Feng-Ping Wang: State Key Laboratory of Food Nutrition & Safety, Tianjin University of Science and Technology, Tianjin, PR China; Key Laboratory of Industrial Fermentation Microbiology, (Ministry of Education), Tianjin University of Science and Technology, Tianjin, PR China.
  2. Xiang-Jun Zhao: State Key Laboratory of Food Nutrition & Safety, Tianjin University of Science and Technology, Tianjin, PR China; Key Laboratory of Industrial Fermentation Microbiology, (Ministry of Education), Tianjin University of Science and Technology, Tianjin, PR China.
  3. Fazli Wahid: State Key Laboratory of Food Nutrition & Safety, Tianjin University of Science and Technology, Tianjin, PR China; Key Laboratory of Industrial Fermentation Microbiology, (Ministry of Education), Tianjin University of Science and Technology, Tianjin, PR China.
  4. Xue-Qing Zhao: State Key Laboratory of Food Nutrition & Safety, Tianjin University of Science and Technology, Tianjin, PR China; Key Laboratory of Industrial Fermentation Microbiology, (Ministry of Education), Tianjin University of Science and Technology, Tianjin, PR China.
  5. Xiao-Tong Qin: State Key Laboratory of Food Nutrition & Safety, Tianjin University of Science and Technology, Tianjin, PR China; Key Laboratory of Industrial Fermentation Microbiology, (Ministry of Education), Tianjin University of Science and Technology, Tianjin, PR China.
  6. He Bai: China Offshore Environm Serv Ltd, Tianjin, 300457, PR China.
  7. Yan-Yan Xie: State Key Laboratory of Food Nutrition & Safety, Tianjin University of Science and Technology, Tianjin, PR China; Key Laboratory of Industrial Fermentation Microbiology, (Ministry of Education), Tianjin University of Science and Technology, Tianjin, PR China.
  8. Cheng Zhong: State Key Laboratory of Food Nutrition & Safety, Tianjin University of Science and Technology, Tianjin, PR China; Key Laboratory of Industrial Fermentation Microbiology, (Ministry of Education), Tianjin University of Science and Technology, Tianjin, PR China. Electronic address: czhong@tust.edu.cn.
  9. Shi-Ru Jia: State Key Laboratory of Food Nutrition & Safety, Tianjin University of Science and Technology, Tianjin, PR China; Key Laboratory of Industrial Fermentation Microbiology, (Ministry of Education), Tianjin University of Science and Technology, Tianjin, PR China.

Abstract

Bacterial cellulose (BC) is a substrate material with high purity and robust mechanical strength, but due to its small pore size and relatively expensive price, it is restricted as an oil-/water separation membrane. In this study, cheaper plant cellulose needle-leaf bleached kraft pulp (NBKP) was added to BC to increase the pore size of the composite membrane, and a superhydrophobic/superoleophilic membrane was prepared for oil-/water separation. The modified membrane surface displayed a petal-like micro-structure and a water contact angle (WCA) of 162.3°, while the oil contact angle was decreased to 0°. What's more, the membrane exhibited excellent oil-/water separation under gravity, recyclability, and a separation efficiency (>95 %), and it was both pH and salt resistant. The membrane also remained durably hydrophobic after 10 separation cycles. And the separation methodology is expected to be highly energy-efficient.

Keywords

MeSH Term

Cellulose
Gluconacetobacter xylinus
Gravitation
Green Chemistry Technology
Hydrogen-Ion Concentration
Hydrophobic and Hydrophilic Interactions
Lignin
Membranes, Artificial
Oils
Plant Leaves
Polysaccharides
Polysaccharides, Bacterial
Porosity
Tensile Strength
Water

Chemicals

Membranes, Artificial
Oils
Polysaccharides
Polysaccharides, Bacterial
Water
hemicellulose
Cellulose
Lignin

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