Oxidative stability of high oleic sunflower oil during deep-frying process of purple potato .

Raffaele Romano, Gioacchino Filosa, Fabiana Pizzolongo, Alessandra Durazzo, Massimo Lucarini, Patricia Severino, Eliana B Souto, Antonello Santini
Author Information
  1. Raffaele Romano: Department of Agriculture, University of Napoli Federico II, Via Università 100, 80055, Portici, Napoli, Italy.
  2. Gioacchino Filosa: Department of Agriculture, University of Napoli Federico II, Via Università 100, 80055, Portici, Napoli, Italy.
  3. Fabiana Pizzolongo: Department of Agriculture, University of Napoli Federico II, Via Università 100, 80055, Portici, Napoli, Italy.
  4. Alessandra Durazzo: CREA-Research Centre for Food and Nutrition, Via Ardeatina 546, 00178, Rome, Italy.
  5. Massimo Lucarini: CREA-Research Centre for Food and Nutrition, Via Ardeatina 546, 00178, Rome, Italy.
  6. Patricia Severino: University of Tiradentes (UNIT), Industrial Biotechnology Program, Av. Murilo Dantas 300, 49032-490, Aracaju, Brazil.
  7. Eliana B Souto: Department of Pharmaceutical Technology, Faculty of Pharmacy, University of Coimbra, Pólo das Ciências da Saúde, Azinhaga de Santa Comba, 3000-548, Coimbra, Portugal.
  8. Antonello Santini: Department of Pharmacy, University of Napoli Federico II, Via. D. Montesano 49, 80131, Napoli, Italy.

Abstract

The behaviour of high oleic sunflower oil in deep frying process of purple potato has been evaluated simulating a fast food cooking process. This oil was used for 8h/day for 6 days, filling up from the 2nd day. A discontinuous and prolonged procedure was tested. Free Fatty Acidity (FFA), Peroxide Value (PV), Total Polar Compounds (TPC), Fatty Acid (FA) composition, Volatile Organic Compounds (VOC) have been determined at different times in thermo-oxidized (T-OX) oil, and in frying oil. The FFA in T-OX oil samples showed values in the range 0.09%-0.24%, whereas in the frying oil values varied in a range between 0.09% and 0.16%. TPCs values varied from 1.76% to 38.24% in T-OX oils, whereas in frying oil used for frying purple potatoes (FOPP) showed values in the range from 1.76 to 29.13%. The peroxides values did not follow a regular pattern, both during thermo-oxidation and during frying. Among the Long Chain Fatty Acids (LCFAs), oleic acid was the most represented (84.13%). Short chain fatty acids (SCFAs) amount was 0.34% (octanoic acid). Medium chain fatty acids (MCFA) amount was 4.45% (palmitic acid). During the thermo-oxidation, the poly-unsaturated fatty acids (PUFA) amount decreased during the 48 h of heat treatment, reaching an amount of 6.21%. This determined the increase in short chain fatty acids (SCFA). Trans fatty acids increased with the frying time. Unsaturated fatty acids (UFA) reached the value of 90.19%; SFA was 9.79%, and octanoic acid was 0.20%. A correlation between TPC vs UFA/SFA and TPC vs C18:2/C16:0 was observed in the frying oil. The most abundant volatile compounds in frying oil (from 0 to 48 h) were the aldehydes produced by decomposition of hydroperoxides of oleic and linoleic acids.

Keywords

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