OpenLB
Open Library of Bioscience
Advanced Search
Small (Weinheim an der Bergstrasse, Germany)
Oct, 2023;19 (41): e2302818.

Single-Ion Polymer Electrolyte Based on Lithium-Rich Imidazole Anionic Porous Aromatic Framework for High Performance Lithium-Ion Batteries.

Zhangnan Li, Liying Wang, Yuhan Liu, Mengxuan Yu, Baijun Liu, Yongfeng Men, Zhaoyan Sun, Wei Hu, Guangshan Zhu
Author Information
  1. Zhangnan Li: Faculty of Chemistry, Northeast Normal University, Changchun, 130024, P. R. China.
  2. Liying Wang: Faculty of Chemistry, Northeast Normal University, Changchun, 130024, P. R. China.
  3. Yuhan Liu: Faculty of Chemistry, Northeast Normal University, Changchun, 130024, P. R. China.
  4. Mengxuan Yu: Faculty of Chemistry, Northeast Normal University, Changchun, 130024, P. R. China.
  5. Baijun Liu: Faculty of Chemistry, Jilin University, Changchun, 130012, P. R. China.
  6. Yongfeng Men: State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022, P. R. China.
  7. Zhaoyan Sun: State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022, P. R. China.
  8. Wei Hu: Faculty of Chemistry, Northeast Normal University, Changchun, 130024, P. R. China. ORCID
  9. Guangshan Zhu: Faculty of Chemistry, Northeast Normal University, Changchun, 130024, P. R. China.
PMID: 37283476 DOI: 10.1002/smll.202302818

Abstract

The low ionic conductivity and Li transference number ( ) of solid polymer electrolytes (SPEs) seriously hinder their application in lithium-ion batteries (LIBs). In this study, a novel single-ion lithium-rich imidazole anionic porous aromatic framework (PAF-220-Li) is designed. The abundant pores in PAF-220-Li are conducive to the Li transfer. Imidazole anion has low binding force with Li . The conjugation of imidazole and benzene ring can further reduce the binding energy between Li and anions. Thus, only Li moved freely in the SPEs, remarkably reducing the concentration polarization and inhibiting lithium dendrite growth. PAF-220-quasi-solid polymer electrolyte (PAF-220-QSPE) is prepared through solution casting of Bis(trifluoromethane)sulfonimide lithium (LiTFSI) infused PAF-220-Li and Poly(vinylidene fluoride-co-hexafluoropropylene)(PVDF-HFP), and possessed excellent electrochemical performance. The electrochemical property are further improved by preparing all-solid polymer electrolyte (PAF-220-ASPE) via pressing-disc method, which has a high Li conductivity of 0.501 mS cm and of 0.93. The discharge specific capacity at 0.2 C of Li//PAF-220-ASPE//LFP reached 164 mAh g , and the capacity retention rate is 90% after 180 cycles. This study provided a promising strategy for SPE with single-ion PAFs to achieve high-performance solid-state LIBs.

Keywords

imidazole porous aromatic frameworks single-ion polymer electrolytes solid-state lithium-ion batteries

References

N. Liu, Z. Lu, J. Zhao, M. T. McDowell, H. W. Lee, W. Zhao, Y. Cui, Nat. Nanotechnol. 2014, 9, 187.
C. K. Chan, H. Peng, G. Liu, K. McIlwrath, X. F. Zhang, R. A. Huggins, Y. Cui, Nat. Nanotechnol. 2008, 3, 31.
X. Han, Y. Gong, K. K. Fu, X. He, G. T. Hitz, J. Dai, A. Pearse, B. Liu, H. Wang, G. Rubloff, Y. Mo, V. Thangadurai, E. D. Wachsman, L. Hu, Nat. Mater. 2017, 16, 572.
M. S. Kim, J. H. Ryu, Deepika, Y. R. Lim, I. W. Nah, K. R. Lee, L. A. Archer, W. I. Cho, Nat. Energy 2018, 3, 889.
M. Martinez-Ibañez, E. Sanchez-Diez, L. X. Qiao, Y. Zhang, X. Judez, A. Santiago, I. Aldalur, J. Carrasco, H. J. Zhu, M. Forsyth, M. Armand, H. Zhang, Adv. Funct. Mater. 2020, 30, 2000455.
G. Xi, M. Xiao, S. J. Wang, D. M. Han, Y. N. Li, Y. Z. Meng, Adv. Funct. Mater. 2021, 31, 2007598.
Z. P. Wan, D. N. Lei, W. Yang, C. Liu, K. Shi, X. G. Hao, L. Shen, W. Lv, B. H. Li, Q. H. Yang, F. Y. Kang, Y. B. He, Adv. Funct. Mater. 2019, 29, 1805301.
P. Fan, H. Liu, V. Marosz, N. T. Samuels, S. L. Suib, L. Y. Sun, L. B. Liao, Adv. Funct. Mater. 2021, 31, 2101380.
J. Q. Sun, C. H. He, X. M. Yao, A. Q. Song, Y. G. Li, Q. H. Zhang, C. Y. Hou, Q. W. Shi, H. Z. Wang, Adv. Funct. Mater. 2021, 31, 2006381.
H. Li, Y. F. Du, X. M. Wu, J. Y. Xie, F. Lian, Adv. Funct. Mater. 2021, 31, 2103049.
I. Shaji, D. Diddens, N. Ehteshami, M. Winter, J. R. Nair, Energy Storage Mater. 2022, 44, 263.
J. Duan, L. Huang, T. Wang, Y. Huang, H. Fu, W. Wu, W. Luo, Y. Huang, Adv. Funct. Mater. 2020, 30, 1908701.
N. Wu, Y. T. Li, A. Dolocan, W. Li, H. H. Xu, B. Y. Xu, N. S. Grundish, Z. M. Cui, H. B. Jin, J. B. Goodenough, Adv. Funct. Mater. 2020, 30, 2000831.
C. Wang, H. Liu, Y. H. Liang, D. B. Li, X. X. Zhao, J. X. Chen, W. W. Huang, L. Gao, L. Z. Fan, Adv. Funct. Mater. 2023, 33, 2209828.
C. Cao, Y. Li, Y. Y. Feng, C. Peng, Z. Y. Li, W. Feng, Energy Storage Mater. 2019, 19, 401.
L. X. Qiao, U. Oteo, Y. Zhang, S. R. Pena, M. Martínez-Ibanez, A. Santiago, R. Cid, L. Meabe, H. Manzano, J. Carrasco, H. Zhang, M. Armand, Energy Storage Mater. 2020, 32, 225.
J. D. Zhu, Z. Zhang, S. Zhao, A. S. Westover, I. Belharouak, P. F. Cao, Adv. Energy Mater. 2021, 11, 2003836.
Y. Hu, N. Dunlap, S. Wan, S. Lu, S. Huang, I. Sellinger, M. Ortiz, Y. Jin, S. Lee, W. Zhang, J. Am. Chem. Soc. 2019, 141, 7518.
J. Y. Zou, A. Trewin, T. Ben, S. L. Qiu, Angew. Chem. 2020, 132, 779.
K. Jeong, S. Park, G. Y. Jung, S. H. Kim, Y. H. Lee, S. K. Kwak, S. Y. Lee, J. Am. Chem. Soc. 2019, 141, 5880.
Y. Du, H. Yang, J. M. Whiteley, S. Wan, Y. Jin, S. H. Lee, W. Zhang, Angew. Chem., Int. Ed. 2016, 55, 1737.
W. Huang, X. Li, X. Yang, X. Zhang, H. Wang, H. Wang, Mater. Chem. Front. 2021, 5, 3593.
S. J. Xu, Z. H. Sun, C. G. Sun, F. Li, K. Chen, Z. H. Zhang, G. J. Hou, H. M. Cheng, F. Li, Adv. Funct. Mater. 2020, 30, 2007172.
T. T. Ma, R. Zhao, J. Song, X. T. Jing, Y. Y. Tian, G. S. Zhu, ACS Appl. Mater. Interfaces 2022, 14, 25601.
X. Wang, S. P. Huang, K. Guo, Y. L. Min, Q. J. Xu, Adv. Funct. Mater. 2022, 32, 2206976.
H. J. Zhao, N. P. Deng, W. M. Kang, Z. J. Li, G. Wang, B. W. Cheng, Energy Storage Mater. 2020, 26, 334.
J. R. Wang, S. Q. Li, Q. Zhao, C. Song, Z. G. Xue, Adv. Funct. Mater. 2021, 31, 2008208.
W. H. Meyer, Adv. Mater. 1998, 10, 439.
W. Y. Liu, C. J. Yi, L. P. Li, S. L. Liu, Q. Y. Gui, D. L. Ba, Y. Y. Li, D. L. Peng, J. P. Liu, Angew. Chem., Int. Ed. 2021, 60, 12931.
L. Chen, W. X. Li, L. Z. Fan, C. W. Nan, Q. Zhang, Adv. Funct. Mater. 2019, 29, 1901047.
C. C. Li, B. S. Qin, Y. F. Zhang, A. Varzi, S. Passerini, J. Y. Wang, J. M. Dong, D. L. Zeng, Z. H. Liu, H. S. Cheng, Adv. Energy Mater. 2019, 9, 1803422.
C. Cao, Y. Li, Y. Y. Feng, P. Long, H. R. An, C. Q. Qin, J. K. Han, W. S. Li, W. Feng, J. Mater. Chem. A. 2017, 5, 22519.
Y. Du, H. S. Yang, J. M. Whiteley, S. Wan, Y. H. Jin, S. H. Lee, W. Zhang, Angew. Chem., Int. Ed. 2016, 55, 1737.
J. Seo, G. Lee, J. Hur, M. Sung, J. Seo, D. Kim, Adv. Energy Mater. 2021, 11, 2102583.
H. Chen, H. Tu, C. Hu, Y. Liu, D. Dong, Y. Sun, Y. Dai, S. Wang, H. Qian, Z. Lin, L. Chen, J. Am. Chem. Soc. 2018, 140, 896.
D. A. Vazquez-Molina, G. S. Mohammad-Pour, C. Lee, M. W. Logan, X. Duan, J. K. Harper, F. J. Uribe-Romo, J. Am. Chem. Soc. 2016, 138, 9767.
Y. M. Jin, C. J. Liu, Z. G. Jia, X. Zong, D. Li, M. Y. Fu, J. H. Wei, Y. P. Xiong, J. Alloy. Compd. 2021, 874, 159890.
T. Yuan, Z. Tan, C. Ma, J. Yang, Z. Ma, S. Zheng, Adv. Energy Mater. 2017, 7, 1601625.
Q. W. Lu, Y. B. He, Q. P. Yu, B. H. Li, Y. V. Kaneti, Y. W. Yao, F. Y. Kang, Q. H. Yang, Adv. Mater. 2017, 29, 1604460.
Z. Li, Z. W. Liu, Z. Y. Li, T. X. Wang, F. L. Zhao, X. S. Ding, W. Feng, B. H. Han, Adv. Funct. Mater. 2020, 30, 1909267.
H. P. Wu, Y. Cao, H. P. Su, C. Wang, Angew. Chem., Int. Ed. 2018, 57, 1361.
J. Atik, D. Diddens, J. H. Thienenkamp, G. Brunklaus, M. Winter, E. Paillard, Angew. Chem., Int. Ed. 2021, 60, 11919.
Z. Zhang, Y. Huang, G. Z. Zhang, L. Chao, Energy Storage Mater. 2021, 41, 631.
S. Lee, J. Jeong, J. Moon, M. Kim, K. V. L. Amarasinghe, K. Y. Chung, H. D. Lim, D. Whang, Chem. Eng. J. 2021, 424, 130527.
Y. F. Zhang, Y. Z. Chen, Y. Liu, B. S. Qin, Z. H. Yang, Y. B. Sun, D. L. Zeng, A. varzi, S. Passerini, Z. H. Liu, H. S. Cheng, J. Power Sources 2018, 397, 79.
D. Guo, D. B. Shinde, W. Shin, E. Abou-Hamad, A. Emwas, Z. P. Lai, A. Manthiram, Adv. Mater. 2022, 34, 2201410.
X. R. Li, Y. Tian, L. Shen, Z. B. Qu, T. Q. Ma, F. Sun, X. Y. Y. Liu, C. Zhang, J. Q. Shen, X. Y. Li, L. N. Gao, S. X. Xiao, T. F. Liu, Y. Liu, Y. F. Lu, Adv. Funct. Mater. 2021, 31, 2009718.
A. D. Becke, J. Chem. Phys. 1993, 98, 5648.
S. Grimme, S. Ehrlich, L. Goerigk, J. Comput. Chem. 2011, 32, 1456.
C. Q. Niu, W. J. Luo, C. M. Dai, C. B. Yu, Y. X. Xu, Angew. Chem., Int. Ed. 2021, 60, 24915.
Z. N. Li, L. Y. Wang, M. X. Yu, Y. H. Liu, B. J. Liu, Z. Y. Sun, W. Hu, G. S. Zhu, ACS Appl. Mater. Interfaces. 2022, 14, 53798.

Grants

  1. 52073044/National Natural Science Foundation of China
  2. U21A20330/National Natural Science Foundation of China
  3. 51873076/National Natural Science Foundation of China
  4. 52073118/National Natural Science Foundation of China
  5. B18012/111
  6. 20220201124GX/Science and Technology Development Plan of Jilin Province
  7. 2021C036-2/Jilin Provincial Development and Reform Commission
  8. 21ZY32/Key R & D plan of Changchun Science and Technology Bureau
  9. /Open Research Fund of State Key Laboratory of Polymer Physics and Chemistry
  10. /Changchun Institute of Applied Chemistry
  11. 2022-19/Chinese Academy of Sciences
Journal Article

Word Cloud

Similar Articles

Cited By