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Heliyon
Jan 15, 2024;10 (1): e23667.

Degradation of reactive red 198 dye from aqueous solutions by combined technology advanced sonofenton with zero valent iron: Characteristics/ effect of parameters/kinetic studies.

Hossein Kamani, Mehrnaz Hosseinzehi, Mehdi Ghayebzadeh, Ali Azari, Seyed Davoud Ashrafi, Hossein Abdipour
Author Information
  1. Hossein Kamani: Infectious Diseases and Tropical Medicine Research Center, Research Institute of Cellular and Molecular Sciences in Infectious Diseases, Zahedan University of Medical Sciences, Zahedan, Iran.
  2. Mehrnaz Hosseinzehi: Infectious Diseases and Tropical Medicine Research Center, Research Institute of Cellular and Molecular Sciences in Infectious Diseases, Zahedan University of Medical Sciences, Zahedan, Iran.
  3. Mehdi Ghayebzadeh: Infectious Diseases and Tropical Medicine Research Center, Research Institute of Cellular and Molecular Sciences in Infectious Diseases, Zahedan University of Medical Sciences, Zahedan, Iran.
  4. Ali Azari: Sirjan School of Medical Sciences, Sirjan, Iran.
  5. Seyed Davoud Ashrafi: Department of Environmental Health Engineering, Research Center of Health and Environment, School of Health, Guilan University of Medical Sciences, Rasht, Iran.
  6. Hossein Abdipour: Student Research Committee, Department of Environmental Health Engineering, Hamadan University of Medical Sciences, Hamadan, Iran.
PMID: 38187256 DOI: 10.1016/j.heliyon.2023.e23667

Abstract

Dyes are one of the most common contaminants in industrial effluents, whose continuous release into the environment has become an increasing global concern. In this work, nanoparticles of zero-valent iron (NZVI) were synthesized using the chemical regeneration method ،and were utilized for the first time as a catalyst in the advanced Sono-Nano-Fenton hybrid method for the decomposition of Reactive Red 198 (RR198). The properties of zero-valent iron nanoparticles were analyzed using SEM and XRD. The effect of pH, initial dye concentration, nanoparticle dosage, zero-valent iron and HO concentration on the decomposition efficiency of Red Reactive 198 was investigated. Comparing the efficiency of Reactivate 198 dye degradation in Sonolysis, Sono-NZVI, Sono-HO and Sono-Nano Fenton processes showed that 97 % efficiency was achieved by the Sono-Nano Fenton process in 60 min. The kinetics of the removal process showed that this process follows pseudo-first-order kinetics and the Langmuir-Hinshelwood model. The results indicate that the effectiveness of the ultrasonic process in removing resistant organic pollutants such as dyes increases tremendously with the synergy of the Fenton process.

Keywords

Degradation Kinetics Nanoparticles zero valent iron (NZVI) Sono nanofenton reactive red 198

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