On the specificity of the oxygenation of unsaturated fatty acids catalyzed by soybean lipoxidase. - National Genomics Data Center (CNCB-NGDC)

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On the specificity of the oxygenation of unsaturated fatty acids catalyzed by soybean lipoxidase.

M Hamberg, B Samuelsson

Author Information

PMID: 6070850

No abstract text available.

Carbon Isotopes

Catalysis

Chemical Phenomena

Chemistry, Physical

Fatty Acids

Keto Acids

Models, Structural

Oxidation-Reduction

Oxygenases

Glycine max

Spectrophotometry

Spectrum Analysis

Tritium

Carbon Isotopes

Fatty Acids

Keto Acids

Tritium

Oxygenases

Journal Article

The origin and structures of dimeric fatty acids from the anaerobic reaction between soya-bean lipoxygenase, linoleic acid and its hydroperoxide.An anaerobic reaction between lipoxygenase, linoleic acid and its hydroperoxides.Effects of alpha-tocopherol and ascorbyl palmitate on the isomerization and decomposition of methyl linoleate hydroperoxides.Specificity of flaxseed lipoxidase.Dimorphotheca sinuata lipoxygenase: formation of 13-L-hydroperoxy-cis-9,trans- 11-octadecadienoic acid from linoleic acid.Isolation of a pure isomer of linoleic acid hydroperoxide.Formation of 11-trans slow reacting substances.A simple assay for lipid hydroperoxides based on triphenylphosphine oxidation and high-performance liquid chromatography.Inevitable generation of primary alcohols during reduction of oxidized lipids with sodium borohydride.Stereochemistry of hydrogen removal during oxygenation of linoleic acid by singlet oxygen and synthesis of 11(S)-deuterium-labeled linoleic acid.

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