Fluoride sorption by nano-hydroxyapatite/chitin composite.

C Sairam Sundaram, Natrayasamy Viswanathan, S Meenakshi
Author Information
  1. C Sairam Sundaram: Department of Science and Humanities, Karaikal Polytechnic College, Karaikal 609609, Puducherry, India. sairam adithya@yahoo.com

Abstract

In this study the fluoride adsorption potential of novel nano-hydroxyapatite/chitin (n-HApCh) composite was explored. The sorbent was characterized using FTIR studies. The effects of pH, interfering anions and contact time were studied. The sorption data obtained under optimized conditions were subjected to Langmuir and Freundlich isotherms. Kinetic studies indicate that the rate of sorption of fluoride on n-HApCh composite follows pseudo-second-order and pore diffusion patterns. n-HApCh composite possesses higher defluoridation capacity (DC) of 2840 mg F(-)kg(-1) than nano-hydroxyapatite (n-HAp) which showed a DC of 1296 mg F(-) kg(-1). Field trials were conducted with the sample collected from a nearby fluoride endemic area.

MeSH Term

Adsorption
Anions
Chitin
Diffusion
Durapatite
Fluorides
Hydrogen-Ion Concentration
Hydroxyapatites
Kinetics
Nanoparticles
Nanotechnology
Thermodynamics
Time Factors
Water Pollutants, Chemical
Water Purification

Chemicals

Anions
Hydroxyapatites
Water Pollutants, Chemical
Chitin
Durapatite
Fluorides

Word Cloud

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