Dissolution of a liquid microdroplet in a nonideal liquid-liquid mixture far from thermodynamic equilibrium.

Pietro Poesio, Gian Paolo Beretta, Todd Thorsen
Author Information
  1. Pietro Poesio: Università degli Studi di Brescia, 25123 Brescia, Italy. pietro.poesio@ing.unibs.it

Abstract

A droplet placed in a liquid-liquid solution is expected to grow, or shrink, in time as approximately t;{1/2}. In this Letter, we report experimental evidence that when the composition in the interface is far from thermodynamic equilibrium due to the nonideality of the mixture, a droplet shrinks as approximately t. This scaling is due to the coupling between mass and momentum transfer known as Korteweg forces as a result of which the droplet self-propels around. The consequent hydrodynamic convection greatly enhances the mass transfer between the droplet and the bulk phase. Thus, the combined effect of nonideality and nonequilibrium modifies the dynamical behavior of the dissolving droplet.

MeSH Term

Acetone
Alkanes
Diffusion
Dimethylpolysiloxanes
Kinetics
Microfluidics
Solutions
Thermodynamics

Chemicals

Alkanes
Dimethylpolysiloxanes
Solutions
Acetone
baysilon
n-hexadecane

Word Cloud

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