Excited-state polarizabilities of solvated molecules using cubic response theory and the polarizable continuum model.

Lara Ferrighi, Luca Frediani, Kenneth Ruud
Author Information
  1. Lara Ferrighi: Department of Chemistry, Centre for Theoretical and Computational Chemistry, University of Tromso, N-9037 Tromso, Norway.

Abstract

The theory and an implementation of the solvent contribution to the cubic response function for the polarizable continuum model for multiconfigurational self-consistent field wave functions is presented. The excited-state polarizability of benzene, para-nitroaniline, and nitrobenzene has been obtained from the double residue of the cubic response function calculated in the presence of an acetonitrile and dioxane solvent. The calculated excited-state polarizabilities are compared to results obtained from the linear response function of the explicitly optimized excited states.

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