1-(3-Chloro-4-fluoro-phen-yl)-5-(2-diazo-acet-yl)-4-phenyl-pyrrolidin-2-one.

Jayanta Kumar Ray, Pranab Haldar, M Canle L, M I Fernández P, J A Santaballa
Author Information

Abstract

In the title compound, C(18)H(13)ClFN(3)O(2), the pyrrolidine ring adopts an envelope conformation and the planar part is rotated by 4.3 (6)° from the plane of the benzene ring and is almost perperdicular both to the diazo-acetyl unit [dihedral angle = 78.93 (7)°] and the phenyl ring [dihedral angle = 86.07 (7)°]. In the crystal, mol-ecules are linked into a three-dimensional framework by C-H⋯O inter-actions. The mol-ecular conformation is stabilized by an intra-molecular C-H⋯O hydrogen bond.

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Grants

  1. I01 BX002286/BLRD VA

Word Cloud

Created with Highcharts 10.0.0ringconformation[dihedralangle=7°]C-H⋯OtitlecompoundC18H13ClFN3O2pyrrolidineadoptsenvelopeplanarpartrotated43 6°planebenzenealmostperperdiculardiazo-acetylunit7893 phenyl8607 crystalmol-eculeslinkedthree-dimensionalframeworkinter-actionsmol-ecularstabilizedintra-molecularhydrogenbond1-3-Chloro-4-fluoro-phen-yl-5-2-diazo-acet-yl-4-phenyl-pyrrolidin-2-one

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