Ru(II) -mediated hydrogen transfer from aqueous glycerol to CO2: from waste to value-added products.

Angela Dibenedetto, Paolo Stufano, Francesco Nocito, Michele Aresta
Author Information
  1. Angela Dibenedetto: Department of Chemistry and CIRCC, University of Bari, Campus Universitario, via Orabona 4-70126 Bari, Italy. a.dibenedetto@chimica.uniba.it

Abstract

Aqueous glycerol was used as the hydrogen source for the reduction of CO(2) to the hydrogen carrier formic acid in the presence of the catalyst [RuCl(2)(PPh(3))(3)]. All intermediates were identified and characterized. glycerol was converted into glycolic acid, HO-CH(2)-COOH, that was identified by using (1)H and (13)C NMR spectroscopy.

MeSH Term

Carbon Dioxide
Glycerol
Hydrogen
Hydrogenation
Recycling
Ruthenium
Water

Chemicals

Water
Carbon Dioxide
Ruthenium
Hydrogen
Glycerol