Extraction of explosives from soil followed by gas chromatography-mass spectrometry analysis with negative chemical ionization.

Erik Holmgren, Stefan Ek, Anders Colmsjö
Author Information
  1. Erik Holmgren: FOI, Swedish Defence Research Agency, Department of Energetic Materials, S-147 25 Tumba, Sweden. erik.holmgren@foi.se

Abstract

A new, simple and accurate method for extraction of explosives from soil was developed and validated. The method includes one hour gentle extraction of compounds from soil in acetonitrile:dichloromethane 50:50 at 30°C. Further analysis was made with GC-MS using cool on-column injection and negative chemical ionization. The method increased the recovery of the more volatile products, generated higher accuracy and was extensively time-saving compared to the conventional EPA (US Environmental Protection Agency) 8330 method. Applications are demonstrated on commercial reference materials.

MeSH Term

Acetonitriles
Explosive Agents
Gas Chromatography-Mass Spectrometry
Limit of Detection
Liquid-Liquid Extraction
Methylene Chloride
Reproducibility of Results
Soil
Temperature

Chemicals

Acetonitriles
Explosive Agents
Soil
Methylene Chloride
acetonitrile