(N→B)-4-Methyl-3-pyrid-yl[N-methyl-imino-diacetate-O,O',N]borane.

Marek Dąbrowski, Krzysztof Durka, Janusz Serwatowski
Author Information
  1. Marek Dąbrowski: Physical Chemistry Department, Faculty of Chemistry, Warsaw University of, Technology, Noakowskiego 3, 00-664 Warsaw, Poland.

Abstract

The title compound, C(11)H(13)BN(2)O(4), has a rigid bicyclic structure due to an intra-molecular nitro-gen-boron dative bond. The B atom is in a distorted tetra-hedron environment with a B-N bond length of 1.640 (2) Å, which is in good comparison with the values in analogues compounds. In the crystal, the mol-ecules are linked by weak C-H⋯O and C-H⋯N inter-actions, forming a three-dimensional network.

References

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Word Cloud

Created with Highcharts 10.0.02bondtitlecompoundC11H13BNO4rigidbicyclicstructuredueintra-molecularnitro-gen-borondativeBatomdistortedtetra-hedronenvironmentB-Nlength1640  Ågoodcomparisonvaluesanaloguescompoundscrystalmol-eculeslinkedweakC-H⋯OC-H⋯Ninter-actionsformingthree-dimensionalnetworkN→B-4-Methyl-3-pyrid-yl[N-methyl-imino-diacetate-OO'N]borane

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