Biomolecule-assisted synthesis of carbon nitride and sulfur-doped carbon nitride heterojunction nanosheets: An efficient heterojunction photocatalyst for photoelectrochemical applications.
Hua Bing Tao, Hong Bin Yang, Jiazang Chen, Jianwei Miao, Bin Liu
Author Information
Hua Bing Tao: School of Chemical and Biomedical Engineering, Nanyang Technological University, 62 Nanyang Drive, Singapore 637459, Singapore.
Hong Bin Yang: School of Chemical and Biomedical Engineering, Nanyang Technological University, 62 Nanyang Drive, Singapore 637459, Singapore.
Jiazang Chen: School of Chemical and Biomedical Engineering, Nanyang Technological University, 62 Nanyang Drive, Singapore 637459, Singapore.
Jianwei Miao: School of Chemical and Biomedical Engineering, Nanyang Technological University, 62 Nanyang Drive, Singapore 637459, Singapore.
Bin Liu: School of Chemical and Biomedical Engineering, Nanyang Technological University, 62 Nanyang Drive, Singapore 637459, Singapore.
A biomolecule-assisted pyrolysis method has been developed to synthesize sulfur-doped graphitic carbon nitride (CNS) nanosheets. During the synthesis, sulfur could be introduced as a dopant into the lattice of carbon nitride (CN). Sulfur doping changed the texture as well as relative band positions of CN. By growing CN on preformed sulfur-doped CN nanosheets, composite CN/CNS heterojunction nanosheets were constructed, which significantly enhanced the photoelectrochemical performance as compared with various control counterparts including CN, CNS and physically mixed CN and CNS (CN+CNS). The enhanced photoelectrochemical performance of CN/CNS heterojunction nanosheets could be ascribed to the efficient separation of photoexcited charge carriers across the heterojunction interface. The strategy of designing and preparing CN/CNS heterojunction photocatalysts in this work can open up new directions for the construction of all CN-based heterojunction photocatalysts.
