N-heterocyclic carbene-main-group chemistry: a rapidly evolving field. - National Genomics Data Center (CNCB-NGDC)

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N-heterocyclic carbene-main-group chemistry: a rapidly evolving field.

Yuzhong Wang, Gregory H Robinson

Author Information

Yuzhong Wang: Department of Chemistry, The University of Georgia , Athens, Georgia 30602-2556, United States.

PMID: 25343222 DOI: 10.1021/ic502231m

This Award Article targets the evolving, yet surprisingly fruitful, chemistry of N-heterocyclic carbenes with low-oxidation-state main-group elements. Specifically, the chemistry of carbene-stabilized diatomic allotropes, diborenes, gallium octahedra, beryllium borohydride, and a host of related compounds will be presented. Providing a valuable historical perspective, the foundational work concerning the organometallic chemistry of gallium with sterically demanding m-terphenyl ligands from this laboratory will also be discussed.

Journal Article

Abnormal N-heterocyclic carbene main group organometallic chemistry: a debut to the homogeneous catalysis.Applications of N-heterocyclic imines in main group chemistry.Anionic tethered N-heterocyclic carbene chemistry.N-Heterocyclic Carbene Adducts of Main Group Elements and Their Use as Ligands in Transition Metal Chemistry.Advances in chemistry of N-heterocyclic carbene boryl radicals.Correction: Advances in chemistry of N-heterocyclic carbene boryl radicals.N-Heterocyclic carbene metal complexes in medicinal chemistry.Carbenaporphyrins: No Longer Missing Ligands in N-Heterocyclic Carbene Chemistry.The N-heterocyclic carbene chemistry of transition-metal carbonyl clusters.N-Heterocyclic carbene chemistry of iron: fundamentals and applications.

Main group chemistry: Small silicon oxides isolated.Stabilization of elusive silicon oxides.A step-for-step main-group replica of the Fischer carbene synthesis at a borylene carbonyl.Unusual nuclear exchange within a germanium-containing aromatic ring that results in germanium atom transfer.Generation of 1,2-azaboretidines reduction of ADC borane adducts.From stable Sb- and Bi-centered radicals to a compound with a Ga=Sb double bond.The SiH radical supported by two N-heterocyclic carbenes.Phosphine and carbene azido-cations: [(L)N] and [(L)N].N-Heterocyclic Carbenes Carrying Weakly Coordinating Anions.Cationic Phosphorus Compounds Based on a Bis(1-piperidinyl)-Substituted Carbodiphosphorane: Syntheses, Structures, and C -H Activation.

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