Green remediation and recycling of contaminated sediment by waste-incorporated stabilization/solidification.

Lei Wang, Daniel C W Tsang, Chi-Sun Poon
Author Information
  1. Lei Wang: Department of Civil and Environmental Engineering, Hong Kong Polytechnic University, Hung Hom, Kowloon, Hong Kong, China.
  2. Daniel C W Tsang: Department of Civil and Environmental Engineering, Hong Kong Polytechnic University, Hung Hom, Kowloon, Hong Kong, China. Electronic address: dan.tsang@polyu.edu.hk.
  3. Chi-Sun Poon: Department of Civil and Environmental Engineering, Hong Kong Polytechnic University, Hung Hom, Kowloon, Hong Kong, China.

Abstract

Navigational/environmental dredging of contaminated sediment conventionally requires contained marine disposal and continuous monitoring. This study proposed a green remediation approach to treat and recycle the contaminated sediment by means of stabilization/solidification enhanced by the addition of selected solid wastes. With an increasing amount of contaminated sediment (20-70%), the 28-d compressive strength of sediment blocks decreased from greater than 10MPa to slightly above 1MPa. For augmenting the cement hydration, coal fly ash was more effective than lime and ground seashells, especially at low sediment content. The microscopic and spectroscopic analyses showed varying amounts of hydration products (primarily calcium hydroxide and calcium silicate hydrate) in the presence of coal fly ash, signifying the influence of pozzolanic reaction. To facilitate the waste utilization, cullet from beverage glass bottles and bottom ashes from coal combustion and waste incineration were found suitable to substitute coarse aggregate at 33% replacement ratio, beyond which the compressive strength decreased accordingly. The mercury intrusion porosimetry analysis indicated that the increase in the total pore area and average pore diameter were linearly correlated with the decrease of compressive strength due to waste replacement. All the sediment blocks complied with the acceptance criteria for reuse in terms of metal leachability. These results suggest that, with an appropriate mixture design, contaminated sediment and waste materials are useful resources for producing non-load-bearing masonry units or fill materials for construction uses.

Keywords

MeSH Term

Calcium Compounds
Calcium Hydroxide
Coal Ash
Environmental Restoration and Remediation
Geologic Sediments
Green Chemistry Technology
Metals
Oxides
Recycling
Silicates
Waste Products

Chemicals

Calcium Compounds
Coal Ash
Metals
Oxides
Silicates
Waste Products
lime
Calcium Hydroxide
calcium silicate

Word Cloud

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