A low-bandgap (1.33 eV) Sn-based MA FA Pb Sn I perovskite is developed via combined compositional, process, and interfacial engineering. It can deliver a high power conversion efficiency (PCE) of 14.19%. Finally, a four-terminal all-perovskite tandem solar cell is demonstrated by combining this low-bandgap cell with a semitransparent MAPbI cell to achieve a high efficiency of 19.08%.