Preparation of Nano-Copper Sulfide and Its Adsorption Properties for 17��-Ethynyl Estradiol.

Sifeng Zhang, Wenxiang Meng, Lulu Wang, Lingxin Li, Yanju Long, Yunrui Hei, Luting Zhou, Shenglan Wu, Ziguang Zheng, Lijun Luo, Fengzhi Jiang
Author Information
  1. Sifeng Zhang: School of Chemical Science and Technology, Yunnan University, Kunming, 650091, China.
  2. Wenxiang Meng: School of Chemical Science and Technology, Yunnan University, Kunming, 650091, China.
  3. Lulu Wang: School of Chemical Science and Technology, Yunnan University, Kunming, 650091, China.
  4. Lingxin Li: School of Chemical Science and Technology, Yunnan University, Kunming, 650091, China.
  5. Yanju Long: School of Chemical Science and Technology, Yunnan University, Kunming, 650091, China.
  6. Yunrui Hei: School of Chemical Science and Technology, Yunnan University, Kunming, 650091, China.
  7. Luting Zhou: School of Chemical Science and Technology, Yunnan University, Kunming, 650091, China.
  8. Shenglan Wu: School of Chemical Science and Technology, Yunnan University, Kunming, 650091, China.
  9. Ziguang Zheng: School of Chemical Science and Technology, Yunnan University, Kunming, 650091, China.
  10. Lijun Luo: School of Chemistry and Environment, Yunnan Minzu University, Kunming, 650500, China.
  11. Fengzhi Jiang: School of Chemical Science and Technology, Yunnan University, Kunming, 650091, China. fengzhij@ynu.edu.cn.

Abstract

In the present work, a tubular nano-copper sulfide was successfully synthesized by hydrothermal method. The physical and chemical properties of the prepared materials were characterized by XRD, SEM, TEM, and BET. The synthesized copper sulfide was used as an adsorbent for removing 17��-ethynyl estradiol (EE2) and exhibited excellent adsorption properties. At 25�����C, 15���mg of adsorbent was applied for 50���mL of 5���mg/L EE2 solution, adsorption equilibrium was reached after 180���min, and the adsorption rate reached nearly 90%. In addition, the kinetics, isothermal adsorption, and thermodynamics of the adsorption process were discussed on the basis of theoretical calculations and experimental results. The theoretical maximum adsorption capacity of copper sulfide was calculated to be 147.06���mg/g. The results of this study indicated that copper sulfide was a stable and efficient adsorbent with promising practical applications.

Keywords

References

  1. Chemosphere. 1998 Apr;36(10):2149-73 [PMID: 9566294]
  2. J Hazard Mater. 2010 Mar 15;175(1-3):970-6 [PMID: 19945220]
  3. Nanoscale Res Lett. 2014 Sep 03;9(1):462 [PMID: 25258598]
  4. Water Res. 2003 Aug;37(14):3530-7 [PMID: 12834747]
  5. Nat Commun. 2012;3:1053 [PMID: 22968699]
  6. Environ Toxicol. 2006 Apr;21(2):181-91 [PMID: 16528694]
  7. J Hazard Mater. 2009 Apr 15;163(1):58-64 [PMID: 18667272]
  8. Nanoscale Res Lett. 2017 Aug 23;12(1):507 [PMID: 28836179]
  9. J Hazard Mater. 2008 Jun 30;155(1-2):334-41 [PMID: 18241984]
  10. Neurotoxicol Teratol. 1999 Jul-Aug;21(4):381-92 [PMID: 10440482]
  11. J Colloid Interface Sci. 2014 May 15;422:16-24 [PMID: 24655823]
  12. Reprod Toxicol. 2013 Jul;38:1-15 [PMID: 23411111]
  13. Environ Sci Technol. 2009 Jan 15;43(2):548 [PMID: 36823802]
  14. Water Res. 2014 Jun 1;56:246-57 [PMID: 24686091]
  15. Environ Int. 2014 Aug;69:104-19 [PMID: 24825791]
  16. Science. 2000 Feb 25;287(5457):1471-3 [PMID: 10688792]
  17. Nano Lett. 2007 Mar;7(3):778-84 [PMID: 17324003]
  18. J Environ Manage. 2019 Dec 01;251:109587 [PMID: 31561142]
  19. Environ Sci Technol. 2017 Jun 6;51(11):6352-6359 [PMID: 28494154]

Grants

  1. No. 2176030135/National Natural Science Foundation of China
  2. No. 21767030/National Natural Science Foundation of China
  3. No. 2017-1-S-12305/Major Project of Kunming Science and Technology Bureau

Word Cloud

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