Considerations for a More Accurate Evaluation Method for Photocatalytic Water Splitting.

Shuang Cao, Lingyu Piao
Author Information
  1. Shuang Cao: CAS Center for Excellence in Nanoscience, National Center for Nanoscience and Technology, CAS Key Laboratory of Standardization and Measurement for Nanotechnology, Beijing, 100190, P. R. China.
  2. Lingyu Piao: CAS Center for Excellence in Nanoscience, National Center for Nanoscience and Technology, CAS Key Laboratory of Standardization and Measurement for Nanotechnology, Beijing, 100190, P. R. China. ORCID

Abstract

Over the past decades, various photocatalysts have been developed and great progress has been achieved in the field of solar-driven photocatalytic water splitting. However, the lack of an accurate and comprehensive evaluation method greatly hinders the meaningful comparison between different systems and becomes a serious impediment for the development of photocatalysts. Although many researchers are aware of this, there has been little work in this area. In this Viewpoint, we first analyze the insufficiencies of the existing evaluation methods and then make preliminary suggestions, aiming to stimulate discussion in the research community and hopefully lead to a widely accepted and authoritative evaluation system to assess photocatalyst performance.

Keywords

References

  1. Q. Xiang, B. Cheng, J. Yu, Angew. Chem. Int. Ed. 2015, 54, 11350-11366;
  2. Angew. Chem. 2015, 127, 11508-11524.
  3. A. Fujishima, K. Honda, Nature 1972, 238, 37-38.
  4. F. Liu, R. Rui, Z. Wang, Y. Weng, C. M. Che, Y. Chen, Angew. Chem. Int. Ed. 2019, 58, 11791-11795;
  5. Angew. Chem. 2019, 131, 11917-11921.
  6. X. B. Li, C. H. Tung, L. Z. Wu, Angew. Chem. Int. Ed. 2019, 58, 10804-10811;
  7. Angew. Chem. 2019, 131, 10918-10925.
  8. L. Lin, Z. Yu, X. Wang, Angew. Chem. Int. Ed. 2019, 58, 6164-6175;
  9. Angew. Chem. 2019, 131, 6225-6236.
  10. Y. Gogotsi, R. M. Penner, ACS Nano 2018, 12, 2081-2083.
  11. E. J. Luber, J. M. Buriak, ACS Nano 2013, 7, 4708-4714.
  12. J. M. Buriak, C. W. Jones, P. V. Kamat, K. S. Schanze, G. C. Schatz, G. D. Scholes, P. S. Weiss, Chem. Mater. 2016, 28, 3525-3526.
  13. D. Voiry, M. Chhowalla, Y. Gogotsi, N. A. Kotov, Y. Li, R. M. Penner, R. E. Schaak, P. S. Weiss, ACS Nano 2018, 12, 9635-9638.
  14. Y. Kawamata, P. S. Baran, Joule 2020, 4, 701-704.
  15. T. Maschmeyer, M. Che, Angew. Chem. Int. Ed. 2010, 49, 1536-1539;
  16. Angew. Chem. 2010, 122, 1578-1582.
  17. H. Kisch, Angew. Chem. Int. Ed. 2010, 49, 9588-9589;
  18. Angew. Chem. 2010, 122, 9782-9783.
  19. M. Qureshi, K. Takanabe, Chem. Mater. 2017, 29, 158-167.
  20. H. Kisch, D. Bahnemann, J. Phys. Chem. Lett. 2015, 6, 1907-1910.
  21. J. M. Buriak, P. V. Kamat, K. S. Schanze, ACS Appl. Mater. Interfaces 2014, 6, 11815-11816.
  22. M. Melchionna, P. Fornasiero, ACS Catal. 2020, 10, 5493-5501.
  23. S. Cao, C. J. Wang, W. F. Fu, Y. Chen, ChemSusChem 2017, 10, 4306-4323.
  24. S. Cao, Y. Chen, C. J. Wang, X. J. Lv, W. F. Fu, Chem. Commun. 2015, 51, 8708-8711.
  25. X. B. Li, C. H. Tung, L. Z. Wu, Nat. Rev. Chem. 2018, 2, 160-173.
  26. S. Fukuzumi, J. Jung, Y. Yamada, T. Kojima, W. Nam, Chem. Asian J. 2016, 11, 1138-1150.
  27. H. J. Kuhn, S. E. Braslavsky, R. Schmidt, Pure Appl. Chem. 2004, 76, 2105-2146.
  28. M. Formenti, F. Juillet, P. Mériaudeau, S. J. Teichner, Chem. Technol. 1971, 1, 680-686.
  29. M. Schiavello, V. Augugliaro, L. Palmisano, J. Catal. 1991, 127, 332-341.
  30. N. Serpone, R. Terzian, D. Lawless, P. Kennepohl, G. Sauve, J. Photochem. Photobiol. A 1993, 73, 11-16.
  31. J. R. Bolton, Solar Energy 1996, 57, 37-50.
  32. D. M. Fabian, S. Hu, N. Singh, F. A. House, T. Hisatomi, K. Domen, F. E. Osterloh, S. Ardo, Energy Environ. Sci. 2015, 8, 2825-2850.
  33. X. Chen, L. Liu, P. Y. Yu, S. S. Mao, Science 2011, 331, 746-750.
  34. X. Tao, Y. Zhao, L. Mu, S. Wang, R. Li, C. Li, Adv. Energy Mater. 2018, 8, 1701392.
  35. S. Cao, Y. Chen, C. C. Hou, X. J. Lv, W. F. Fu, J. Mater. Chem. A 2015, 3, 6096-6101.
  36. J. Cai, M. Wu, Y. Wang, H. Zhang, M. Meng, Y. Tian, X. Li, J. Zhang, L. Zheng, J. Gong, Chem 2017, 2, 877-892.
  37. S. Cao, Y. Chen, C. J. Wang, P. He, W. F. Fu, Chem. Commun. 2014, 50, 10427-10429.
  38. R. A. Rather, S. Singh, B. Pal, Sol. Energy Mater. Sol. Cells 2017, 160, 463-469.
  39. Y. Si, S. Cao, Z. Wu, Y. Ji, Y. Mi, X. Wu, X. Liu, L. Piao, Appl. Catal. B 2018, 220, 471-476.
  40. Y. Si, S. Cao, Z. Wu, Y. Ji, Y. Mi, X. Wu, X. Liu, L. Piao, Nano Energy 2017, 41, 488-493.
  41. S. Cao, Y. Chen, H. Wang, J. Chen, X. Shi, H. Li, P. Cheng, X. Liu, M. Liu, L. Piao, Joule 2018, 2, 549-557.
  42. B. Han, Y. H. Hu, J. Phys. Chem. C 2015, 119, 18927-18934.
  43. W. Luo, Z. Yang, Z. Li, J. Zhang, J. Liu, Z. Zhao, Z. Wang, S. Yan, T. Yu, Z. Zou, Energy Environ. Sci. 2011, 4, 4046-4051.
  44. S. Chen, T. Takata, T. Domen, Nat. Rev. Mater. 2017, 2, 17050.
  45. H. Cheng, X. Lv, S. Cao, Z. Y. Zhao, Y. Chen, W. F. Fu, Sci. Rep. 2016, 6, 19846.
  46. J. Liu, Y. Liu, N. Liu, Y. Han, X. Zhang, H. Huang, Y. Lifshitz, S. T. Lee, J. Zhong, Z. Kang, Science 2015, 347, 970-974.
  47. Q. Wang, T. Hisatomi, Q. Jia, H. Tokudome, M. Zhong, C. Wang, Z. Pan, T. Takata, M. Nakabayashi, N. Shibata, Y. Li, I. Sharp, A. Kudo, T. Yamada, K. Domen, Nat. Mater. 2016, 15, 611-616.

Grants

  1. 21703046/National Natural Science Foundation of China
  2. 21972028/National Natural Science Foundation of China
  3. XDB36000000/Strategic Priority Research Program of Chinese Academy of Sciences

Word Cloud

Created with Highcharts 10.0.0evaluationphotocatalystswatersplittingpastdecadesvariousdevelopedgreatprogressachievedfieldsolar-drivenphotocatalyticHoweverlackaccuratecomprehensivemethodgreatlyhindersmeaningfulcomparisondifferentsystemsbecomesseriousimpedimentdevelopmentAlthoughmanyresearchersawarelittleworkareaViewpointfirstanalyzeinsufficienciesexistingmethodsmakepreliminarysuggestionsaimingstimulatediscussionresearchcommunityhopefullyleadwidelyacceptedauthoritativesystemassessphotocatalystperformanceConsiderationsAccurateEvaluationMethodPhotocatalyticWaterSplittingH2productionanalyticalchemistryphotocatalysis

Similar Articles

Cited By