Most of the supramolecular structures lack accuracy at the macroscopic scale because of their spontaneous uncontrolled self-assembly. Although significant progress has been made in understanding the pros and cons of various directional noncovalent interactions and their specific molecular recognition ability, it is only in the recent past that the focus has been shifted toward controlling the dimension, dispersity, and other macroscopic properties of supramolecular assemblies. In this context, recent examples encompass various external stimuli to gain the structural precision in supramolecular assembly, among which light-triggered supramolecular assembly has gained significant interest as it is reagent free and endows the possibility of the controlled synthesis of supramolecular assemblies via manipulation of the light energy, irradiation time, or spatial control. This mini-review highlights representative recent examples of phototriggered supramolecular assemblies (from the monomer or another type of assembly) by removal of a photolabile protecting group, photoisomerization, or other methods of photoactivation of a dormant building block.
