Construction of Inverse Metal-Zeolite Interfaces via Area-Selective Atomic Layer Deposition.
Peng Zhai, Laibao Zhang, David A Cullen, Divakar R Aireddy, Kunlun Ding
Author Information
Peng Zhai: Department of Chemical Engineering, Louisiana State University, Baton Rouge, Louisiana 70803, United States.
Laibao Zhang: Department of Chemical Engineering, Louisiana State University, Baton Rouge, Louisiana 70803, United States.
David A Cullen: Center for Nanophase Materials Sciences, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831, United States. ORCID
Divakar R Aireddy: Department of Chemical Engineering, Louisiana State University, Baton Rouge, Louisiana 70803, United States.
Kunlun Ding: Department of Chemical Engineering, Louisiana State University, Baton Rouge, Louisiana 70803, United States. ORCID
The spatial confinement at metal-zeolite interfaces offers a powerful knob to steer the selectivity of chemical reactions on metal catalysts. However, encapsulating metal catalysts into small-pore zeolites remains a challenging task. Here, we demonstrate an inverse design of metal-zeolite interfaces, "" constructed by area-selective atomic layer deposition. This inverse design bypasses the intrinsic synthetic issues associated with metal encapsulation, offering a potential solution for the fabrication of task-specific metal-zeolite interfaces for desired catalytic applications. Infrared spectroscopy and several probe reactions confirmed the spatial confinement effects at the inverse metal-zeolite interfaces.
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