Selective hydrogenolysis of biomass-derived glycerol to propanediol is important for producing high value-added chemicals from renewable resources but faces a huge challenge. Here we report a transition metal doped Pt/TiO catalyst with incorporated Cr, Mo, or W oxides, which exhibits the selective formation of 1,2-propanediol or 1,3-propanediol with a yield from 51.2% to 82.5% toward glycerol hydrogenolysis. In situ experimental studies verify that the surrounding CrO decreases the hydrogenating ability of Pt, leading to the formation of 1,2-propanediol, while the MoO or WO brings the Brønsted acid, giving 1,3-propanediol. This modification based on the catalyst compositions alters the reaction pathway with a different adsorption and bond scission mechanism, which can be extended to other sustainable catalytic systems.
