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Aug, 2023;23 (8): e202200301.

Ion Transport in Glyme- and Sulfolane-Based Highly Concentrated Electrolytes.

Keisuke Shigenobu, Taku Sudoh, Junichi Murai, Kaoru Dokko, Masayoshi Watanabe, Kazuhide Ueno
Author Information
  1. Keisuke Shigenobu: Department of Chemistry and Life Science, Yokohama National University, 79-5 Tokiwadai, Hodogaya-ku, Yokohama, 240-8501, Japan.
  2. Taku Sudoh: Department of Chemistry and Life Science, Yokohama National University, 79-5 Tokiwadai, Hodogaya-ku, Yokohama, 240-8501, Japan.
  3. Junichi Murai: Department of Chemistry and Life Science, Yokohama National University, 79-5 Tokiwadai, Hodogaya-ku, Yokohama, 240-8501, Japan.
  4. Kaoru Dokko: Department of Chemistry and Life Science, Yokohama National University, 79-5 Tokiwadai, Hodogaya-ku, Yokohama, 240-8501, Japan.
  5. Masayoshi Watanabe: Institute of Advanced Sciences, Y, okohama National University, 79-5 Tokiwadai, Hodogaya-ku, Yokohama, 240-8501, Japan.
  6. Kazuhide Ueno: Department of Chemistry and Life Science, Yokohama National University, 79-5 Tokiwadai, Hodogaya-ku, Yokohama, 240-8501, Japan. ORCID
PMID: 36802142 DOI: 10.1002/tcr.202200301

Abstract

Highly concentrated electrolytes (HCEs) have a similarity to ionic liquids (ILs) in high ionic nature, and indeed some of HECs are found to behave like an IL. HCEs have attracted considerable attention as prospective candidates for electrolyte materials in future lithium secondary batteries owing to their favorable properties both in the bulk and at the electrochemical interface. In this study, we highlight the effects of the solvent, counter anion, and diluent of HCEs on the Li ion coordination structure and transport properties (e. g., ionic conductivity and apparent Li ion transference number measured under anion-blocking conditions, ). Our studies on dynamic ion correlations unveiled the difference in the ion conduction mechanisms in HCEs and their intimate relevance to values. Our systematic analysis of the transport properties of HCEs also suggests the need for a compromise to simultaneously achieve high ionic conductivity and high values.

Keywords

Electrolyte Ion correlation Ionic conductivity Self-diffusion coefficients Solvate ionic liquids

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Grants

  1. 22J11851/JSPS KAKENHI
  2. 20H02837/JSPS KAKENHI
  3. 22K19082/JSPS KAKENHI
  4. 19H05812/JSPS KAKENHI
  5. 22H00340/JSPS KAKENHI
  6. /Japan Society for the Promotion of Science (JSPS)
  7. JPMJAL1301/JST ALCA-SPRING
  8. JPNP20004/JST ALCA-SPRING
  9. /New Energy and Industrial Technology Development Organization (NEDO)
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Created with Highcharts 10.0.0HCEsionicionhighpropertiesconductivityHighlyliquidsLitransportvaluesIonconcentratedelectrolytessimilarityILsnatureindeedHECsfoundbehavelikeILattractedconsiderableattentionprospectivecandidateselectrolytematerialsfuturelithiumsecondarybatteriesowingfavorablebulkelectrochemicalinterfacestudyhighlighteffectssolventcounteraniondiluentcoordinationstructuree gapparenttransferencenumbermeasuredanion-blockingconditionsstudiesdynamiccorrelationsunveileddifferenceconductionmechanismsintimaterelevancesystematicanalysisalsosuggestsneedcompromisesimultaneouslyachieveTransportGlyme-Sulfolane-BasedConcentratedElectrolytesElectrolytecorrelationIonicSelf-diffusioncoefficientsSolvate

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