Supporting Trimetallic Metal-Organic Frameworks on S/N-Doped Carbon Macroporous Fibers for Highly Efficient Electrocatalytic Oxygen Evolution.

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Yafei Zhao, Xue Feng Lu, Zhi-Peng Wu, Zhihao Pei, Deyan Luan, Xiong Wen David Lou

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Yafei Zhao: School of Chemical and Biomedical Engineering, Nanyang Technological University, 62 Nanyang Drive, Singapore, 637459, Singapore.
Xue Feng Lu: State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, 350002, P. R. China.
Zhi-Peng Wu: School of Chemical and Biomedical Engineering, Nanyang Technological University, 62 Nanyang Drive, Singapore, 637459, Singapore.
Zhihao Pei: School of Chemical and Biomedical Engineering, Nanyang Technological University, 62 Nanyang Drive, Singapore, 637459, Singapore.
Deyan Luan: School of Chemical and Biomedical Engineering, Nanyang Technological University, 62 Nanyang Drive, Singapore, 637459, Singapore.
Xiong Wen David Lou: School of Chemical and Biomedical Engineering, Nanyang Technological University, 62 Nanyang Drive, Singapore, 637459, Singapore. ORCID

PMID: 36921278 DOI: 10.1002/adma.202207888

Hybrid materials, integrating the merits of individual components, are ideal structures for efficient oxygen evolution reaction (OER). However, the rational construction of hybrid structures with decent physical/electrochemical properties is yet challenging. Herein, a promising OER electrocatalyst composed of trimetallic metal-organic frameworks supported over S/N-doped carbon macroporous fibers (S/N-CMF@Fe Co Ni -MOF) via a cation-exchange strategy is delicately fabricated. Benefiting from the trimetallic composition with improved intrinsic activity, hollow S/N-CMF matrix facilitating exposure of active sites, as well as their robust integration, the resultant S/N-CMF@Fe Co Ni -MOF electrocatalyst delivers outstanding activity and stability for alkaline OER. Specifically, it needs an overpotential of 296 mV to reach the benchmark current density of 10 mA cm with a small Tafel slope of 53.5 mV dec . In combination with X-ray absorption fine structure spectroscopy and density functional theory calculations, the post-formed Fe/Co-doped γ-NiOOH during the OER operation is revealed to account for the high OER performance of S/N-CMF@Fe Co Ni -MOF.

cation-exchange hollow S/N-doped carbon metal-organic frameworks oxygen evolution reaction

V. R. Stamenkovic, D. Strmcnik, P. P. Lopes, N. M. Markovic, Nat. Mater. 2017, 16, 57.
N. T. Suen, S. F. Hung, Q. Quan, N. Zhang, Y. J. Xu, H. M. Chen, Chem. Soc. Rev. 2017, 46, 337.
J. W. Nai, X. W. Lou, Adv. Mater. 2019, 31, 1706825.
X. F. Lu, Y. Chen, S. B. Wang, S. Y. Gao, X. W. Lou, Adv. Mater. 2019, 31, 1902339.
Z. W. Seh, J. Kibsgaard, C. F. Dickens, I. B. Chorkendorff, J. K. Norskov, T. F. Jaramillo, Science 2017, 355, eaad4998.
A. Grimaud, W. T. Hong, Y. Shao-Horn, J. M. Tarascon, Nat. Mater. 2016, 15, 121.
Z.-F. Huang, J. Song, S. Dou, X. Li, J. Wang, X. Wang, Matter 2019, 1, 1494.
J. Kibsgaard, I. Chorkendorff, Nat. Energy 2019, 4, 430.
X. Xu, F. Song, X. Hu, Nat. Commun. 2016, 7, 12324.
T. Wang, G. Nam, Y. Jin, X. Wang, P. Ren, M. G. Kim, J. Liang, X. Wen, H. Jang, J. Han, Y. Huang, Q. Li, J. Cho, Adv. Mater. 2018, 30, 1800757.
H. Zhang, Y. Liu, T. Chen, J. Zhang, J. Zhang, X. W. Lou, Adv. Mater. 2019, 31, 1904548.
L. Z. Guo, J. F. Sun, J. X. Wei, Y. Liu, L. R. Hou, C. Z. Yuan, Carbon Energy 2020, 2, 203.
W. Cheng, H. Zhang, D. Luan, X. W. Lou, Sci. Adv. 2021, 7, eabg2580.
L. Lin, W. Zhou, R. Gao, S. Yao, X. Zhang, W. Xu, S. Zheng, Z. Jiang, Q. Yu, Y. W. Li, C. Shi, X.-D. Wen, D. Ma, Nature 2017, 544, 80.
S. L. Zhao, Y. Wang, J. C. Dong, C. T. He, H. J. Yin, P. F. An, K. Zhao, X. F. Zhang, C. Gao, L. J. Zhang, J. W. Lv, J. X. Wang, J. Q. Zhang, A. M. Khattak, N. A. Khan, Z. X. Wei, J. Zhang, S. Q. Liu, H. J. Zhao, Z. Y. Tang, Nat. Energy 2016, 1, 16184.
J. J. Duan, S. Chen, C. Zhao, Nat. Commun. 2017, 8, 15341.
H. Wang, Q.-L. Zhu, R. Zou, Q. Xu, Chem 2017, 2, 52.
Y. Fang, D. Luan, S. Gao, X. W. Lou, Angew. Chem., Int. Ed. 2021, 60, 20102.
W. Cheng, X. F. Lu, D. Y. Luan, X. W. Lou, Angew. Chem., Int. Ed. 2020, 59, 18234.
Y. Hou, M. Qiu, M. G. Kim, P. Liu, G. Nam, T. Zhang, X. Zhuang, B. Yang, J. Cho, M. Chen, C. Yuan, L. Lei, X. Feng, Nat. Commun. 2019, 10, 1392.
Y. Zhao, Y. Guo, X. F. Lu, D. Luan, X. Gu, X. W. Lou, Adv. Mater. 2022, 34, 2203442.
H. Zhou, Y. Zhao, J. Gan, J. Xu, Y. Wang, H. Lv, S. Fang, Z. Wang, Z. Deng, X. Wang, P. Liu, W. Guo, B. Mao, H. Wang, T. Yao, X. Hong, S. Wei, X. Duan, J. Luo, Y. Wu, J. Am. Chem. Soc. 2020, 142, 12643.
Y. Zhao, H. Zhou, W. Chen, Y. Tong, C. Zhao, Y. Lin, Z. Jiang, Q. Zhang, Z. Xue, W.-C. Cheong, B. Jin, F. Zhou, W. Wang, M. Chen, X. Hong, J. Dong, S. Wei, Y. Li, Y. Wu, J. Am. Chem. Soc. 2019, 141, 10590.
Y. Zhao, H. Zhou, X. Zhu, Y. Qu, C. Xiong, Z. Xue, Q. Zhang, X. Liu, F. Zhou, X. Mou, W. Wang, M. Chen, Y. Xiong, X. Lin, Y. Lin, W. Chen, H.-J. Wang, Z. Jiang, L. Zheng, T. Yao, J. Dong, S. Wei, W. Huang, L. Gu, J. Luo, Y. Li, Y. Wu, Nat. Catal. 2021, 4, 134.
W. Wang, Y. Wu, T. Liu, Y. Zhao, Y. Qu, R. Yang, Z. Xue, Z. Wang, F. Zhou, J. Long, Z. Yang, X. Han, Y. Lin, M. Chen, L. Zheng, H. Zhou, X. Lin, F. Wu, H. Wang, Y. Yang, Y. Li, Y. Dai, Y. Wu, ACS Catal. 2022, 12, 2632.
W. Cheng, Z. P. Wu, D. Luan, S. Q. Zang, X. W. Lou, Angew. Chem., Int. Ed. 2021, 60, 26397.
H. Fei, J. Dong, Y. Feng, C. S. Allen, C. Wan, B. Volosskiy, M. Li, Z. Zhao, Y. Wang, H. Sun, P. An, W. Chen, Z. Guo, C. Lee, D. Chen, I. Shakir, M. Liu, T. Hu, Y. Li, A. I. Kirkland, X. Duan, Y. Huang, Nat. Catal. 2018, 1, 63.
Y. G. Yao, Z. N. Huang, P. F. Xie, L. P. Wu, L. Ma, T. Y. Li, Z. Q. Pang, M. L. Jiao, Z. Q. Liang, J. L. Gao, Y. He, D. J. Kline, M. R. Zachariah, C. M. Wang, J. Lu, T. P. Wu, T. Li, C. Wang, R. S. Yassar, L. B. Hu, Nat. Nanotechnol. 2019, 14, 851.
X. Wan, X. Liu, Y. Li, R. Yu, L. Zheng, W. Yan, H. Wang, M. Xu, J. Shui, Nat. Catal. 2019, 2, 259.
Q. Dong, C. Shuai, Z. Mo, R. Guo, N. Liu, G. Liu, J. Wang, W. Liu, Y. Chen, J. Liu, Y. Jiang, Q. Gao, CrystEngComm 2021, 23, 1172.
Y. Huang, S. L. Zhang, X. F. Lu, Z. P. Wu, D. Luan, X. W. Lou, Angew. Chem., Int. Ed. 2021, 60, 11841.
X. F. Lu, L. Yu, X. W. Lou, Sci. Adv. 2019, 5, eaav6009.
M. Bajdich, M. Garcia-Mota, A. Vojvodic, J. K. Norskov, A. T. Bell, J. Am. Chem. Soc. 2013, 135, 13521.
J. Shan, C. Ye, S. Chen, T. Sun, Y. Jiao, L. Liu, C. Zhu, L. Song, Y. Han, M. Jaroniec, Y. Zhu, Y. Zheng, S. Z. Qiao, J. Am. Chem. Soc. 2021, 143, 5201.
B. Zhang, X. Zheng, O. Voznyy, R. Comin, M. Bajdich, M. García-Melchor, L. Han, J. Xu, M. Liu, L. Zheng, F. P. García de Arquer, C. T. Dinh, F. Fan, M. Yuan, E. Yassitepe, N. Chen, T. Regier, P. Liu, Y. Li, P. D. Luna, A. Janmohamed, H. L. Xin, H. Yang, A. Vojvodic, E. H. Sargent, Science 2016, 352, 333.
S. Zhang, T. Yu, H. Wen, Z. Ni, Y. He, R. Guo, J. You, X. Liu, Chem. Commun. 2020, 56, 15387.
J. N. Lu, J. Liu, L. Z. Dong, S. L. Li, Y. H. Kan, Y. Q. Lan, Chem. - Eur. J. 2019, 25, 15830.
Y. Jin, S. Huang, X. Yue, H. Du, P. K. Shen, ACS Catal. 2018, 8, 2359.
Z. P. Wu, H. Zhang, S. Zuo, Y. Wang, S. L. Zhang, J. Zhang, S. Q. Zang, X. W. Lou, Adv. Mater. 2021, 33, 2103004.

MOE2019-T2-2-049/Academic Research Fund

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