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Environmental science and pollution research international
Feb, 2024;31 (9): 12748-12779.

Advancements in textile dye removal: a critical review of layered double hydroxides and clay minerals as efficient adsorbents.

Giphin George, Anu Mary Ealias, Manickam Puratchiveeran Saravanakumar
Author Information
  1. Giphin George: Department of Mechanical Engineering, Koneru Lakshmaiah Education Foundation, Vaddeswaram, A.P., Green Fields, 522302, India. giphingeorge@gmail.com. ORCID
  2. Anu Mary Ealias: Department of Civil Engineering, Koneru Lakshmaiah Education Foundation, Vaddeswaram, A.P., Green Fields, 522302, India.
  3. Manickam Puratchiveeran Saravanakumar: Department of Environmental and Water Resources Engineering, School of Civil Engineering, VIT, Vellore, 632014, India.
PMID: 38265587 DOI: 10.1007/s11356-024-32021-w

Abstract

The textile industry is responsible for producing large volumes of wastewater that contain a wide variety of dye compounds. This poses a significant environmental hazard and risks harming both ecosystems and living organisms. This review study explores the advancements in adsorption research for dye removal, with a particular emphasis on the development of various adsorbents. The article provides detailed insights into the toxicity and classification of dyes, different treatment techniques, and the characteristics of numerous adsorbents, with special attention to layered double hydroxides (LDH) and clay minerals. A comprehensive list of adsorbents, encompassing natural materials, agricultural by-products, industrial waste, and activated carbon, is discussed for effective removal of different dyes. Furthermore, the review extensively examines the influence of various adsorption variables, such as pH, initial dye concentration, adsorbent dosage, temperature, contact time, ionic strength, and pore volume of the adsorbent. Additionally, the application of response surface methodology for optimizing adsorption variables is elucidated. Commonly, electrostatic attraction, ��-�� interactions, n-�� interactions, van der Waals forces, H-bonding, and pore diffusion play a major role in adsorption mechanism. The review also found that LDH can eliminate a wide range of dyes from wastewater, achieving excellent uptake capacities often exceeding 500 mg/g, with a removal efficiency of 99%. The Langmuir isotherm and pseudo-second-order kinetic equations gave the best fit to most of the adsorption data. Overall, this review serves as a valuable resource for researchers and practitioners seeking sustainable solutions to address the environmental challenges posed by textile dye contamination.

Keywords

Dye adsorption Isotherm and kinetics Layered double hydroxides Textile dyes Wastewater treatment

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MeSH Term

Wastewater
Clay
Ecosystem
Hydroxides
Coloring Agents
Minerals
Textiles
Adsorption
Water Pollutants, Chemical
Kinetics
Hydrogen-Ion Concentration

Chemicals

Wastewater
Clay
Hydroxides
Coloring Agents
Minerals
Water Pollutants, Chemical
Journal Article Review

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