Green Synthesis of Reduced Graphene Oxide Using the Plant Extract: Exploring Its Potential for Methylene Blue Dye Degradation and Antibacterial Activity.

Ravi Saini, Ranjeet Kumar Mishra, Pradeep Kumar
Author Information
  1. Ravi Saini: Department of Chemical Engineering & Technology, Indian Institute of Technology (BHU), Varanasi 221005, Uttar Pradesh,India.
  2. Ranjeet Kumar Mishra: Department of Chemical Engineering, Manipal Institute of Technology, Manipal Academy of Higher Education, Manipal, Karnataka 576104, India. ORCID
  3. Pradeep Kumar: Department of Chemical Engineering & Technology, Indian Institute of Technology (BHU), Varanasi 221005, Uttar Pradesh,India. ORCID

Abstract

Graphene has attracted significant attention recently due to its unique mechanical, electrical, thermal, and optical properties. The present study focuses on synthesizing green rGO using the plant extract by mixing it in a suspension of graphene oxide. The plant extract of acts as a reducing agent and is cost-effective, renewable, and eco-friendly. Green-synthesized rGO (G-rGO) was characterized using FTIR, HR-SEM, EDX, and HR-XRD analyses. G-rGO consists of nanosheets with an average width of approximately 30 nm. G-rGO has a range of hydrodynamic radius (270-470) nm and an average ζ potential of -29.9 mV. Further, G-rGO was used as a nanoadsorbent for optimal exclusion of methylene blue (MB) dye using the response surface methodology (RSM). Adsorption results confirmed 94.85% MB dye removal with 58.81 mg g adsorption capacity at optimum conditions. The G-rGO's antibacterial activity was also tested against (Gram-positive) and (Gram-negative) bacteria, finding the exhibited zone of inhibition of 10, 11, and 15 mm and 10, 13, and 17 mm at 20, 40, and 80 μg mL concentrations of G-rGO, respectively.

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Word Cloud

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