Platinum-ruthenium-iron embedded in nitrogen-doped ordered mesoporous carbon for adrenaline electrochemical sensing study.

Yuxin Zhao, Tong Zhang, Fangxun Liu, Man Zheng, Kun Shi, Xin Yang, Pinyi Zhao, Xin Li, Yufan Zhang, Huan Wang
Author Information
  1. Yuxin Zhao: Key Laboratory of Analytical Science and Technology of Hebei Province, Key Laboratory of Chemical Biology of Hebei Province, Key Laboratory of Medicinal Chemistry and Molecular Diagnosis, State Key Laboratory of New Pharmaceutical Preparations and Excipients, Ministry of Education, College of Chemistry and Materials Science, Hebei University, Baoding, 071002, Hebei Province, PR China.
  2. Tong Zhang: Key Laboratory of Analytical Science and Technology of Hebei Province, Key Laboratory of Chemical Biology of Hebei Province, Key Laboratory of Medicinal Chemistry and Molecular Diagnosis, State Key Laboratory of New Pharmaceutical Preparations and Excipients, Ministry of Education, College of Chemistry and Materials Science, Hebei University, Baoding, 071002, Hebei Province, PR China.
  3. Fangxun Liu: Key Laboratory of Analytical Science and Technology of Hebei Province, Key Laboratory of Chemical Biology of Hebei Province, Key Laboratory of Medicinal Chemistry and Molecular Diagnosis, State Key Laboratory of New Pharmaceutical Preparations and Excipients, Ministry of Education, College of Chemistry and Materials Science, Hebei University, Baoding, 071002, Hebei Province, PR China.
  4. Man Zheng: Key Laboratory of Analytical Science and Technology of Hebei Province, Key Laboratory of Chemical Biology of Hebei Province, Key Laboratory of Medicinal Chemistry and Molecular Diagnosis, State Key Laboratory of New Pharmaceutical Preparations and Excipients, Ministry of Education, College of Chemistry and Materials Science, Hebei University, Baoding, 071002, Hebei Province, PR China.
  5. Kun Shi: Key Laboratory of Analytical Science and Technology of Hebei Province, Key Laboratory of Chemical Biology of Hebei Province, Key Laboratory of Medicinal Chemistry and Molecular Diagnosis, State Key Laboratory of New Pharmaceutical Preparations and Excipients, Ministry of Education, College of Chemistry and Materials Science, Hebei University, Baoding, 071002, Hebei Province, PR China.
  6. Xin Yang: Key Laboratory of Analytical Science and Technology of Hebei Province, Key Laboratory of Chemical Biology of Hebei Province, Key Laboratory of Medicinal Chemistry and Molecular Diagnosis, State Key Laboratory of New Pharmaceutical Preparations and Excipients, Ministry of Education, College of Chemistry and Materials Science, Hebei University, Baoding, 071002, Hebei Province, PR China.
  7. Pinyi Zhao: Key Laboratory of Analytical Science and Technology of Hebei Province, Key Laboratory of Chemical Biology of Hebei Province, Key Laboratory of Medicinal Chemistry and Molecular Diagnosis, State Key Laboratory of New Pharmaceutical Preparations and Excipients, Ministry of Education, College of Chemistry and Materials Science, Hebei University, Baoding, 071002, Hebei Province, PR China.
  8. Xin Li: Key Laboratory of Analytical Science and Technology of Hebei Province, Key Laboratory of Chemical Biology of Hebei Province, Key Laboratory of Medicinal Chemistry and Molecular Diagnosis, State Key Laboratory of New Pharmaceutical Preparations and Excipients, Ministry of Education, College of Chemistry and Materials Science, Hebei University, Baoding, 071002, Hebei Province, PR China.
  9. Yufan Zhang: Key Laboratory of Analytical Science and Technology of Hebei Province, Key Laboratory of Chemical Biology of Hebei Province, Key Laboratory of Medicinal Chemistry and Molecular Diagnosis, State Key Laboratory of New Pharmaceutical Preparations and Excipients, Ministry of Education, College of Chemistry and Materials Science, Hebei University, Baoding, 071002, Hebei Province, PR China. zyf@hbu.edu.cn.
  10. Huan Wang: Key Laboratory of Analytical Science and Technology of Hebei Province, Key Laboratory of Chemical Biology of Hebei Province, Key Laboratory of Medicinal Chemistry and Molecular Diagnosis, State Key Laboratory of New Pharmaceutical Preparations and Excipients, Ministry of Education, College of Chemistry and Materials Science, Hebei University, Baoding, 071002, Hebei Province, PR China. zwhsjzl@163.com.

Abstract

A novel nitrogen-doped ordered mesoporous carbon (OMC) pore-embedded growth Pt-Ru-Fe nanoparticles (Pt-Ru-Fe@N-OMCs) composite was designed and synthesized for the first time. SBA-15 was used as a template, and dopamine was used as a carbon and nitrogen source and metal linking reagent. The oxidative self-polymerization reaction of dopamine was utilized to polymerize dopamine into two-dimensional ordered SBA-15 template pores. Iron porphyrin was introduced as an iron source at the same time as polymerization of dopamine, which was introduced inside and outside the pores using dopamine-metal linkage. Carbonization of polydopamine, nitrogen doping and iron nanoparticle formation were achieved by one-step calcination. Then the templates were etched to form Fe@N-OMCs, and finally the Pt-Ru-Fe@N-OMCs composites were stabilized by the successful introduction of platinum-ruthenium nanoparticles through the substitution reaction. The composite uniformly embeds the transition metal nanoparticles inside the OMC pores with high specific surface area, which limits the size of the metal nanoparticles inside the pores. At the same time, the metal nanoparticles are also loaded onto the surface of the OMCs, realizing the uniform loading of metal nanoparticles both inside and outside the pores. This enhances the active sites of the composite, promotes the mass transfer process inside and outside the pores, and greatly enhances the electrocatalytic performance of the catalyst. The material shows high electrocatalytic performance for adrenaline, which is characterized by a wide linear range, high sensitivity and low detection limit, and can realize the detection of actual samples.

Keywords

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Grants

  1. 22567620H/the Key Laboratory of Analytical Science and Technology of Hebei Province
  2. 22567635H/Key Laboratory of Chemical Biology of Hebei Province
  3. hxkytd-py2102/the Research Innovation Team of College of Chemistry and Environmental Science of Hebei University
  4. 216Z2605G/the Central Government Guides Local Science and Technology Development Fund Project
  5. 225A4802D/the Innovation Improvement Project of Hebei Province
  6. Supported by Foundation of President of Hebei University/Supported by Foundation of President of Hebei University

Word Cloud

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