Advancing gasoline desulfurization: Multi-objective fuzzy optimization in systems technology.

Stephen S Correa, Kate Andre T Alviar, Angel Nicole V Arbilo, Angelo Earvin Sy Choi
Author Information
  1. Stephen S Correa: Department of Chemical Engineering, De La Salle University, 2401 Taft Ave, Manila, 0922, Philippines.
  2. Kate Andre T Alviar: Department of Chemical Engineering, De La Salle University, 2401 Taft Ave, Manila, 0922, Philippines.
  3. Angel Nicole V Arbilo: Department of Chemical Engineering, De La Salle University, 2401 Taft Ave, Manila, 0922, Philippines.
  4. Angelo Earvin Sy Choi: Department of Chemical Engineering, De La Salle University, 2401 Taft Ave, Manila, 0922, Philippines.

Abstract

Ultrasonic-assisted oxidative desulfurization (UAOD) is utilized to lessen environmental problems due to sulfur emissions. The process uses immiscible polar solvents and ultrasonic waves to enhance desulfurization efficiency. Prior research focused on comparing the effectiveness of UAOD for gasoline using response surface methodology. This study evaluates the desulfurization efficiency and operating costs, including ultrasonic power, irradiation time, and oxidant amount to determine optimal conditions. The study used a multi-objective fuzzy optimization (MOFO) approach to evaluate the economic viability of UAOD for gasoline. It identified upper and lower boundaries and then optimized the desulfurization efficiency and operating costs while considering uncertainty errors. The fuzzy model employed max-min aggregation to optimize the degree of satisfaction on a scale from 0 (unsatisfied) to 1 (satisfied). Optimal conditions for gasoline UAOD were found at 445.43 W ultrasonic power, 4.74 min irradiation time, and 6.73 mL oxidant, resulting in a 66.79 % satisfaction level. This yielded a 78.64 % desulfurization efficiency (Y) at an operating cost of 13.49 USD/L. Compared to existing literature, gasoline desulfurization was less efficient and less costly. The solutions provided by MOFO demonstrate not only economic viability through decreased overall operating costs and simplified process conditions, but also offer valuable insights for optimizing prospective future industrial-scale UAOD processes.

Keywords

References

  1. Ultrason Sonochem. 2019 Oct;57:147-165 [PMID: 31208610]
  2. Ultrason Sonochem. 2020 May;63:104946 [PMID: 31945567]
  3. Ultrason Sonochem. 2021 Dec;81:105858 [PMID: 34894526]

Word Cloud

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