A Novel Multi-Step Global Mechanism Scheme for n-Decane Combustion.

Shaozhuan Xiong, Yantian Bi
Author Information
  1. Shaozhuan Xiong: Research Center of Combustion Aerodynamics, Southwest University of Science and Technology, Mianyang 621000, China.
  2. Yantian Bi: Institute of Mechanics and Aerospace, Southwest University of Science and Technology, Mianyang 621000, China.

Abstract

Based on the directed relation graph with error propagation (DRGEP) reduction method, a detailed mechanism consisting of 119 species and 527 reactions for n-decane was simplified. As a result, a skeletal mechanism comprising 32 species and 73 reactions was derived. Subsequently, the quasi-steady state approximation (QSSA) reduction method was employed to further simplify the skeletal mechanism, resulting in a reduced mechanism with 18 species and 14 global reactions. A comparison between the reduced mechanism, skeletal mechanism, and detailed mechanism revealed that the reduced and skeletal mechanisms successfully replicated the combustion characteristics of the detailed mechanism under a range of initial conditions. These models can be credibly incorporated into large-scale combustion simulation, serving as a solid foundation for enhancing computational efficiency.

Keywords

References

  1. Phys Chem Chem Phys. 2007 Aug 21;9(31):4218-29 [PMID: 17687471]

Grants

  1. 20210305-06/China National Petroleum Corporation division of Southwest Oil

Word Cloud

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